Ion calorimetry: Using mass spectrometry to measure melting points
نویسندگان
چکیده
منابع مشابه
Ion calorimetry: Using mass spectrometry to measure melting points.
Calorimetry measurements have been used to probe the melting of aluminum cluster cations with 63 to 83 atoms. Heat capacities were determined as a function of temperature (from 150 to 1050 K) for size-selected cluster ions using an approach based on multicollision-induced dissociation. The experimental method is described in detail and the assumptions are critically evaluated. Most of the alumi...
متن کاملIon Balance Mass Spectrometry
We have developed a technique to simultaneously compare the cyclotron frequencies of two single ions to obtain atomic mass ratios with fractional accuracies at or below 10−11. Much like a balance scale, this two-ion technique cancels many sources of noise and error – chief among them magnetic field noise. The new mass comparisons are used in combination with γ-ray wavelength measurements, perfo...
متن کاملIon Mobility Mass Spectrometry
for more complex analysers for automated sample processing and plant control. The separation time will continue to decrease; in the past there has been limited interest in fast separations but this could change as automated sample processing is developed. Increasing use of coupled techniques such as GC-GC, liquid chromatography-GC, and supercritical Suid chromatography-GC for the separation of ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of the American Society for Mass Spectrometry
سال: 2007
ISSN: 1044-0305,1879-1123
DOI: 10.1016/j.jasms.2006.08.019